3. FILLER METAL OF MAGNESIUM BASED ALLOYS

Table 3.1 - Chemical Composition Requirments for Magnesium Electrodes
3.1 - Filler metal selection
3.1.1 - General Weldng Considerations
3.1.2 - Weldability and filler metal selection
Table 3.2 - All-weld metal properties of various Magnesium alloys
3.2 - Storage and care of filler metal
Table 3.2 - Guide to the choice of filler metal for gas shielded arc welding

Table 3.1 - Chemical Composition Requirments for Magnesium Electrodes ñ Top

LAC Stock # Mg % Al % Be % Mn min % Zn % Zr % Rare Earth % Cu max, % Fe max, % Ni max, % Si max, % Other Elements Total max, %
4350 REM. 5.8-7.2 0.0002-0.0008 0.15 0.40-1.5 - - 0.05 0.005 0.005 0.05 0.30
4395 REM. 9.5-10.5 0.0002-0.0008 0.13 0.75-1.25 - - 0.05 0.005 0.005 0.05 0.30
4396 REM. 8.3-9.7 0.0002-0.0008 0.15 1.7-2.3 - - 0.05 0.005 0.005 0.05 0.30
M107 REM. - - - 2.0-3.1 0.45-1.0 2.5-4.0 - - - - 0.30

3.1 Filler metal selection.ñ Top

3.1.1 General welding considerationsñ Top

Magnesium is well known for its extreme lightness, excellent machineability and weldability and the high strength-to-weight ratio of its alloys. Its specific gravity is 1.74. On an equal value basis, it weighs roughly one-forth as much as steel, and two-thirds as much as aluminum.

When heated in air to its melting point, magnesium tends to oxidize rapidly. For this reason, welding with magnesium requires the use of a protective shield, such as an inert gas or flux.

Because of its comparatively low melting point, latent heat of fusion and specific heat per unit volume, magnesium requires a relatively small amount of heat to melt. The total heat of fusion is approximately two-thirds that for aluminum and one-fifth that for steel. The high coefficients of thermal expansion (from 65 to 750 ºF about 0.000016 per º F ) and conductivity tend to cause considerable distortion during welding. In this respect, the welding of magnesium is more critical than the welding of steel and similar to the welding of aluminum.

3.1.2 Weldability and filler metal selection. ñ Top

The weldability of most magnesim alloys can be considered good to excellent if proper filler metal is employed. The use of a filler metal with a lower melting point and a wider freezing range than the base metal is advantageous as it improves weldability and minimizes weld cracking. A list of recommended filler metal used with the variuos base metal is given in table 3.2.

Some typical mechanical properties of all-weld metal of various magnesium alloys are shown in table 3.2.

TABLE 3.2 - All-weld metal properties of various Magnesium alloys ñ Top

FILLER ALLOY ULTIMATE TENSILE STRENGTH ( X 10³ PSI) TENSILE YIELD STRENGTH ( X 10³ PSI) % ELONGATION IN 2 INCHES WROUGHT BASE ALLOY
AZ61A 34.3 14.5 10.0 AZ31B
AZ61A 36.2 14.5 16.2 ZE10A
AZ92A 36.8 18.9 8.0 AZ31B
EZ33A 27.8 18.9 4.5 ZE10A
EZ33A 32.0 17.8 9.0 HK31A
EZ33A 26.8 19.8 3.5 HM31A
EZ33A 30.0 21.2 6.3 HM21A

3.2 Storage and care of filler metal. ñ Top

Filler metal cleanliness and freedom from surface oxidation are important in gas shielding arc welding. Oil or other organic material as well as heavy oxide coatings on the surface of the filler metal, will interfere with coalescence of the molten weld pool and cause porosity or other weld defects, or both. For this reason, filler metal is manufactured and packaged in order to prevent contamination.

Proper storage of welding rods and electrodes in the user's plant is essential if the filler metal is to remain free of contamination until used. Packages of filler metal should not be left outdoors or in unheated buildings because the greater variation in temperature and humidity increase the possibility of moisture condensation. Properly protected filler metal can be stored for long periods of time without adverse affect on its performance.

Packages of filler metal should remain sealed until ready for use. Once removed from the container, spooled electrodes should be kept covered, even during use, to prevent surface contamination by dust, moisture, or other airborne foreign material. After welding is completed, the electrode should be returned to its original container for storage. Welding rods should also be kept covered until ready for use. Storage conditions here need not be as rigorous as for spooled electrodes because good welding practice always includes a stainless steel wool rub of the rod just prior to use to remove surface oxidation or other contamination.

TABLE 3.2 - Guide to the choice of filler metal for gas shielded arc welding. ñ Top

BASE ALLOY AM100A AZ10A AZ31B &C AZ61A AZ63A AZ80A AZ81A AZ91C AZ92A EK41A EZ33A HK31A
Filler Alloy
AM100A M107Œ 4395
AZ10A 4395 4350 4395
AZ31B & C 4395 4350 4395 4350 4395
AZ61A 4395 4350 4395 4350 4395 4350 4395
AZ63A M107Œ 4395
AZ80A 4395 4350 4395 4350 4395 4350 4395 4350 4395
AZ81A 4395 4395 4395 4395 4395 M107Œ 4395
AZ91C 4395 4395 4395 4395 4395 4385 M107Œ 4395
AZ92A 4395 4395 4395 4395 4395 4395 4395 M107Œ
EK41A 4395 4395 4395 4395 4395 4395 4395 4395 4396Œ
EZ33A 4395 4395 4395 4395 4395 4395 4395 4395 4396 4396
HK31A 4395 4395 4395 4395 4395 4395 4395 4395 4396 4396 4396Œ
HM21A 4395 4395 4395 4395 4395 4395 4395 4395 4396 4396 4396
HM31A 4395 4395 4395 4395 4395 4395 4395 4395 4396 4396 4396
HZ32A 4395 4395 4395 4395 4395 4395 4395 4395 4396 4396 4396
K1A 4395 4395 4395 4395 4395 4395 4395 4395 4396 4396 4396
M1A MG1 4395 4350 4395 4350 4395 4350 4395 4350 4395 4395 4395 4395 4395 4395 4395
ZE41A Ž Ž Ž Ž Ž Ž Ž Ž 4396 4396 4396
ZK21A 4395 4350 4395 4350 4395 4350 4395 4350 4395 4395 4395 4395 4395 4395 4395
ZH62A ZK51A ZK60A ZK61A
Base Alloy HM21A HM31A HZ32A K1A LA141A M1A
MG1
QE22A ZE10A ZE41A ZK21A ZH62A
ZK51A
AK60A
ZK61A
HM21A 4396
HM31A 4396 4396
HZ32A 4396 4396 4396Œ
K1A 4396 4396 4396 4396Œ
M1A MG1 4395 4395 4395 4395 Ž 4350 4395
ZE41A 4396 4396 4396 4396 Ž Ž 4396 Ž 4396Œ
ZK21A 4395 4395 4395 4395 Ž 4350 4395 4396 4350 4395 4395 4350 4395
ZH62A ZK51A ZK60A ZK61A 4396Œ

Œ Cast alloys are generally welded with filler metal having the same or similar composition as the base metal in order to achieve maximum strength and proper response to post weld heat treatment schedules. Lacking the availability of suitable rods of such alloys, the commercially available filler metal listed will provide equivalent weldability but with the possibility of some reduction in strength.
Welding not recommended
Ž No data available for welding this combination.

Note: When more than one filler metal is listed, they are listed in order of preference.


© Lancaster Alloys Co.